华东理工大学

华东理工大学化学与分子学院硕士研究生导师信息介绍：王利民

一、个人简况

王利民（Wang Limin），教授，博士生导师。

大连理工大学应用化学(精细化工)博士，美国康乃尔大学（Cornell）访问学者。

华东理工大学化学与分子工程学院精细化工系主任，“皮革化学与工程”博士点以及“轻工技术与工程”工程硕士点的导师组组长。

联系方式：上海市梅陇路130号，电话：021-64253881，64252758，64252288，邮编：200237

邮件：wanglimin@ecust.edu.cn

二、研究领域与研究方向、学术团体兼职情况

1．基础研究：金属有机化学(稀土金属有机化学、合成方法学)、有机氟化学（含氟材料）和精细化学品化学（染料、颜料、表面活性剂）

2．应用研究：(1)精细化学品合成（染料、颜料及其中间体、医药中间体、精细有机中间体、功能材料等），(2)表面活性剂及其助剂合成（日用化学品、医药助剂、纺织助剂、轻工助剂、有机硅氟表面活性剂等）

至今已在J. Org. Chem., Adv. Synth.Catal.等国际核心刊物上发表50余篇论文，共被他人引用650余次，单篇最高95次，其中2005年发表于Tetrahedron (Volume61, 6(2005), Pages 1539-1543)的文章获得Tetrahedron Most Cited Paper 2005-2008 Award。申请中国发明专利37项，其中16项已授权。出版有关论（译）著（包括参编或参译）6部。

三、学术团体兼职

美国化学学会会员

中国化工学会精细化工专业委员会委员

全国稀土助染助鞣协作网专家组成员

“应用化学”，“精细化工”，“中国皮革”杂志编委

徐汇区青年科技工作者联谊会理事

四、代表性论文及论著

1. Limin Wang*, Jianjun Xia, He Tian, Fang Qin, Changtao Qian, Jie Sun, Yb(OTf)3 Catalyzed One-Pot Synthesis of Quinazolin-4(3H)-ones from anthranilic acid, amine and orthoesters (or formic acid)  in Solvent-free Conditions. Synthesis, 2003, 8, 1241-1247.

2. Limin Wang*, Changtao Qian, He Qian,Yun Ma, Lanthanide Triflate Catalyzed One-Pot Synthesis of Dihydropyrimidin-2(1H)-thiones by a Three-Component of 1,3-Dicarbonyl Compounds, Aldehydes, and Thiourea Using a Solvent-free Biginelli Condensation,   Synthetic Communications, 2003, 33(9), 1459-1468.

3. Limin Wang*, Jianjun Xia, He Tian, Changtao Qian, Yun Ma, Synthesis of coumarin by Yb(OTf)3 catalyzed Pechmann reaction under the solvent-free conditions, Indian Journal of Chemistry, Section B, 2003, 42B, 2097-2099.

4. Limin Wang*，Jijun Liu, He Tian, Changtao Qian, Ytterbium Triflate Catalyzed Heterocyclization of 1, 2-Phenylenediamines and Alkyloxalates under Solvent-Free Conditions via Phillips Reaction: a facile Synthesis of Quinoxaline-2, 3-diones derivatives. Synth. Commun. 2004, 34, 1349-1355.

5. Limin Wang*, Jia Sheng, He Tian, Jianwei Han, Zhaoyu Fan, Changtao Qian, A Convenient Synthesis of α, α’-Bis(substituted benzylidene)cycloalkanones Catalyzed by Yb(OTf)3 Under Solvent-free Conditions. Synthesis, 2004, 18, 3060-3064.

6. Limin Wang*, Jia Sheng, He Tian, Changtao Qian, An efficient procedure for the synthesis of Benzimidazole derivatives using Yb(OTf)3 as catalyst under solvent-free conditions. Synthetic Communication, 2004, 34(23), 4265-4272.

7. Limin Wang*, Jijun Liu, He Tian, Changtao Qian, Jie Sun, One-pot Synthesis of cis-Isoquinolonic acids derivatives via three-component Reaction of Homophthalic Anhydride with Aldehydes and Amines Using Ytterbium(Ⅲ) Triflate as a Catalyst, Adv. Synth. Catal. 2005, 347(5), 689-694.

8. Limin Wang, Jianwei Han, He Tian, Jia Sheng, Zhaoyu Fan, Xiaoping Tang, Rare earth Perfluorooctanoates[RE(PFO)3]-catalyzed Condensations of Indole with Carbonyl Compounds, Synlett, 2005, 2, 0337-0339.

9. Limin Wang*, Jianwei Han, Jia Sheng, He Tian, Zhaoyu Fan,  Rare earth Perfluorooctanoate [RE(PFO)3] catalyzed one-pot Mannich reaction: Three component synthesis of β-Amino carbonyl compounds, Catalysis communications, 2005, 6(3), 201-204.

10. Limin Wang*, Jia Sheng, Liang zhang, Jianwei Han, Zhao-Yu Fan, He Tian, Facile Yb(OTf)3 Promoted One-Pot Synthesis of Polyhydroquinoline Derivatives Through Hantzsch Reaction. Tetrahedron, 2005, 61(6), 1539-1543.

11. Li-Min Wang*, Jue-Hua Shao, He Tian, Yong-Hong Wang, Bo Liu，Rare Earth Perfluorooctanoate [RE(PFO)3] Catalyzed One-pot Synthesis of Benzopyran Derivatives， Journal of Fluorine Chemistry，2006，127(1)，97-100.

12.Li-Min Wang*, Yong-Hong Wang, He Tian, Yin-fang, Yao, Jue-Hua Shao, Bo Liu, Ytterbium triflate as an efficient catalyst for one-pot synthesis of substituted imidazoles through three-component condensation of benzil, aldehydes and ammonium acetate, Journal of Fluorine Chemistry，2006，127(12)，1570-1573.

13. Yun Ma, Limin Wang*, Juehua Shao, He Tian, Recent Developments of Lewis Acids Catalysis: Lanthanide Catalysts with Long Perfluoro-Chain in Organic, Current Organic Chemistry, 2007, 6(11), 559-576. (IF3.961)

14. Wang, Limin*, Pan Xiaojuan, Fan, Zhaoyu, Yang, Liubo, Liu Lian, Tian, He, Synthesis and Crystal Structure of 4,4'-Diamino-N,N'-diethyl bisbenzenesulfamide, Chinese J. Struct. Chem. 2007, 26, 177-183.

15.Wang, Li-Min* Zhang, Liang, Hu, Liang, Tian, He, Highly One-Pot Synthesis of 2-Arylmethyl-N-Substituted Anilines via Yb(OTf)3 Catalyzed Three-component Reaction, Chinese Journal of Chemistry, 2007, 3(25), 370-374.

16. Limin Wang, Xiaojuan Pan, Feng Wang, He Tian, Liubo Yang, Lian Liu, Structure-properties relationships investigation on the azo dyes derived from benzene sulfonamide intermediates, Dyes and pigments, 2008, 76, 636-645.

17. Wei Shen, Li-Min Wang*, Jian-Jun Feng, He Tian, Highly efficient synthesis of homoallylic alcohols and amines via allylation of aldehydes and imines catalyzed by ZrOCl28H2O in water, Tetrahedron Lett. 49(25), 2008, 4047–4049.

18. Jie Wu, Li-Min Wang*, Ping Zhao, FengWang, Gui-fengWang, A new type of quaternary mmonium salt containing siloxane group and used as favorable dispersant in the surface treatment of C.I. pigment red 170, Progress in Organic Coatings  2008, 63, 189–194.

19. Wei Shen, Li-Min Wang*, He Tian, Quaternary ammonium salt gemini surfactants containing perfluoroalkyl tails catalyzed one-pot Mannich reactions in aqueous media, Journal of Fluorine Chemistry 2008, 129(4), 267–273.

20. Li-Min Wang*, Liang Hu, Jue-Hua Shao, Jianjun Yu, Liang Zhang, A novel catalyst zinc(II)        perfluorooctanoate [Zn(PFO)2]-catalyzed three-component one-pot eaction: Synthesis of quinazolinone derivatives in aqueous micellar media, Journal of Fluorine Chemistry, 2008, 129(12), 1139-1145

21.Wang Li-Min*, Sui Yuan-Yuan, Zhang Liang,  Synthesis of 14-alkyl or aryl-14-H-dibenzo[a,j]xanthenes using Yb(OTf)3 as an efficient catalyst under solvent-free conditions, Chinese Journal of Chemistry, 2008, 26(6), 1105-1108.

22. Li-Min Wang*, Liang Hu, Hong-Juan Chen, Yuan-Yuan Suia, Wei Shen, One-Pot Synthesis of Quinoline-4-carboxylic acid derivatives in water: Ytterbium Perfluorooctanoate Catalyzed Doebner Reaction, Journal of Fluorine Chemistry, 2009, 130(4), 406-409.

23. WANG, Li-Min*, YAO, Yin –Fang,  WANG, Yong-Hong, ZOU, Gang, A highly efficient and environmentally friendly CMC-supported lanthanide catalyst for one-pot synthesis of substituted imidazoles, Chinese Journal of Chemistry, 2009, 27(2), 343-346.

24. Wei Shen, Li-Min Wang*, He Tian, Jun Tang, Jian-jun Yu, Brønsted acidic ionic liquid containing perfluoroalkyl tails catalyzed one-pot synthesis of 1,8-dioxo-decahydroacridines in water, Journal of Fluorine Chemistry, 2009, 130(6), 522-527.

25. Li-Min Wang*, Ning Jiao, Jun Qiu, Jian-Jun Yu, Jin-Qian Liu, Feng-Lou Guo, Ying Liu,    Sodium stearate catalyzed multicomponent reactions for efficient synthesis of spirooxindoles in aqueous micellar media, Tetrahedron, 2010, 66(1) , 339–343.

26. Jian-Jun Yu, Li-Min Wang,* Jin-Qian Liu, Feng-Lou Guo, Ying Liu and Ning Jiao, Synthesis  of tetraketones in water and under catalyst-free conditions, Green Chem., 2010, 12, 216-219.

27. Shen, Wei, Wang, Limin*, Tang, Jun,Qian, Zhenhua,  Tong, Xiaofeng,

Ionic Liquid-coordinated Ytterbium(III) Sulfonate Catalyzed Michael Addition of Indoles to Electron-deficient Nitroolefins, Chinese Journal of Chemistry, 2010, 28, 443-448.

28.Liu, Y.; Wang, L. M*; Sui, Y. Y.; Yu, J. J. Solvent-free Synthesis of Alkylaminophenols via Petasis Boronic Mannich Reaction in One Pot without Catalysts,  Chin. J. Chem. 2010, 28, 2039-2044.

29.Jun Tang , Limin Wang*, Yinfang Yao , Liang Zhang , Wenbo Wang, One-pot synthesis of 2-amino-3-cyanopyridine derivatives catalyzed by ytterbium perfluorooctanoate [Yb(PFO)3]. Tetrahedron Letters,  2011, 52, 509–511

30. Jun Tang, Limin Wang*, WenboWang, LiangZhang, ShengyingWu, DanMao. A facile synthesis of α-aminophosphonates catalyzed by ytterbium perfluorooctanoate under solvent-free conditions. Journal of Fluorine Chemistry, 2011,132, 102-106

31.Jian-Jun Yu, Li-Min Wang,* Feng-Lou Guo, Jin-Qian Liu, Ying Liu,Ning Jiao, Solvent-free Amination of Secondary Benzylic Alcohols with N-Nucleophiles Catalysed by FeCl3, Synthetic Communications, 2011,44(11), 1609-1616

32. Jun Tang, Limin Wang,* Dan Mao, Wenbo Wang, Liang Zhang, Shengying Wu andYongshu Xie,Ytterbium Pentafluorobenzoate as a Novel Fluorous Lewis Acid Catalyst in the Synthesis of 2,4-Disubstituted Quinolines, Tetrahedron,  2011, 67, 8465–8469

33. Jun Tang, Limin Wang*, Shengying Wu, Dan Mao, The advance and application of rare earth perfluorooctanoate [RE(PFO)3], Synlett, 2011, 011， DOI: 10.1055/s-0031-1289558，ASAP

34. Jun Qiu, Limin Wang* , Mingtao Liu, Qiang Shen, Jun Tang, An efficient and simple protocol for a PdCl2-ligandless and additive-free Suzuki coupling reaction of aryl bromides,Tetrahedron Letters, 2011,52 ,6489-6491.

相关论（译）著：

1.《精细有机合成新方法》，王利民，田禾，ISBN7-5025-5198-0/TQ.1925，化学工业出版社，2004年3月出版。

2.《分子器件与分子机器》(Molecular Devices and Machines),V. Balzani等著，田禾，王利民译，ISBN7-5025-6857-3/O.1111,化学工业出版社，2005年6月出版。

3.《应用化学与技术》，现代工程科学与技术丛书，袁渭康总主编，田禾主编，王利民 副主编，ISBN978-7-03-019071-0, 科学出版社，2007年7月出版。

4.《Flourine Chemistry Research Advances》, Editor: Ira V. Gardiner, Chapter 5(Rare Earth Catalysts with Long Perfluoro-chain in Organic Chemistry), Li-Min Wang, Yin-Fang, Yao, Gang Zou, He Tian, ISBN 978-1-60021-730-2, © 2007 Nova Science Publishers, Inc.

5.《精细有机合成工艺》，王利民，邹刚等，ISBN7-5025-5198-0/TQ.1925，化学工业出版社，
2008年1月出版。

6. Advances in Chemistry Research. Volume 7,   Editors: James C. Taylor,Ytterbium: Compounds, Production and Applications, chapter 4, page 127-170, Li-Min Wang, Jun Tang, Jin- Qian Liu, ISBN: 978-1-61122-211-1,© 2011 Nova Science Publishers, Inc.

五、科研项目

1、国家自然科学基金

2、中科院上海有机化学研究所有机氟化学重点实验室开放基金

3、省部攻关项目及国内外大型精细化工和日化企业合作项目

六、部分授权专利：
 
中国 200410024683.0 ZL200410024683.0 含稀土金属的全氟羧酸路易酸催化剂及其制备方法

中国 02151141.1 ZL 02151141.1 一种喹唑啉-4(3H)衍生物的合成方法

中国 200510112349.5 ZL 200510112349.5 阳离子型含氟Gemini表面活性剂

中国 02151142.X ZL 02151142.X 一种无致癌性的单偶氮酸性蓝染料及其应用

中国 02136615.2 ZL 02136615.2 一种有机硅阴离子表面活性剂及其合成方法

中国 200410025014.5 ZL200410025014.5 阳离子、反应型有机硅固色剂及其制备方法

中国 200410079059.0 ZL200410079059.0 一种无致癌性的单偶氮酸性蓝染料及其应用

中国 200610147828.5 ZL200610147828.5 阳离子型Gemini表面活性剂

中国 200610147830.2 ZL200610147830.2 稀土化合物在酰氯化反应中的应用

中国 200710045977.5 ZL200710045977.5 含硅氧链有机硅化合物及其用途

中国 200810040167.5 ZL 200810040167.5 无醛有机硅固色剂

中国 200810062645.2 ZL 200810062645.2 一种阴离子改性氨基硅油织物柔软剂及其制备方法

中国 200810204944.5 ZL200810204944.5 树枝状稀土金属配合物

中国 201010023011.3 ZL201010023011.3 含氟聚硅氧烷及其用途

七、研究生培养

硕士点、博士点招生：应用化学，皮革化学与工程，精细合成化学与分子工程

工程硕士点招生：轻工技术与工程，制药工程

研究生优秀论文:

(1)刘骥军，论文题目：稀土化合物在有机合成中的应用，2005年上海市优秀硕士论文。

(2)盛  佳，论文题目：三氟甲磺酸稀土化合物在有机合成中的应用，2006年上海市优秀硕士论文。

(3)韩建伟，论文题目：新型全氟羧酸稀土催化剂的制备及其在有机合成中应用，2007上海市优秀硕士论文。

(4)潘笑娟，论文题目：磺酰胺系中间体及其偶氮染料的合成与性能研究, 2008上海市优秀硕士论文。

(5)胡亮，全氟辛酸金属盐及其在含水体系中催化的有机合成反应的研究，2009, 华东理工大、学优秀硕士论文

八、获奖

(1)有机光电功能材料与分子机器， 2006年度上海市科学技术奖，一等奖，获奖号：20062038，完成人：田禾，陈彧，朱为宏，王利民，王巧纯。

(2)稀土催化合成高性能有机颜料， 2008年教育部技术发明奖，二等奖，获奖号：2008-115，完成人：田禾, 王利民, 王峰, 苏建华, 陈立荣, 黄卓。

(3)"双子座"(Gemini)硅氟链偕脂肪链季铵盐的合成及应用，2009年教育部技术进步奖，二等奖，获奖号：2009-225，完成人：田禾, 王利民, 施建刚, 李季, 王亚光, 繆惠平。

(4)高性能有机颜料制备新工艺，2009年上海市技术发明奖，二等奖，获奖号：20093003-2-R02，完成人：田禾,王利民,王峰,陈立荣,黄卓,王桂峰,杨柳波。