河北大学

河北大学化学与环境科学学院研究生导师武奎介绍如下：

1、个人简介

武奎，男，2013年6月在山东大学晶体材料国家重点实验室获得工学博士学位(硕博连读);2013.7-2018.8在中科院新疆理化所工作，任副研究员;2018.9进入河北大学工作，任特聘研究员。近十年间一直从事光电功能晶体材料的研发工作，到目前为止在材料、光学以及化学等杂志上以第一和通讯作者发表文章32

篇，其中第一 18 篇，通讯 14篇)，其中包括国际知名杂志Coord. Chem. Rev.(1篇)，J. Am. Chem. Soc.(2篇)，Angew. Chem. Int. Ed.(1篇)，chemical sciences (1篇)，Chem. Mater.(1篇)，Chem. Commun.(2篇)。申请中国发明专利14项(授权 6 项)。研究成果获2015年新疆第十届青年学术年会优秀论文一等

奖，2016年自治区自然科学优秀学术论文二等奖，并在《Science Foundation in China》期刊上宣传报道。入选2017年“万人计划”后备人选-青年拔尖人才(全疆3人)、自治区青年科技创新人才培养工程，主持国家自然科学基金面上和青年基金、中科院装备研制项目、中科院西部之光、自治区自然科学基金、重

点实验室开放课题等。获得荣誉有2014年新疆自治区科技进步一等奖、2015年乌鲁木齐市科技进步一等奖，2012年研究生国家奖学金、新疆创新创业大赛奖。

邮箱：wukui@ms.xjb.ac.cn

热烈欢迎各位学生报考研究生，欢迎到化学楼207(办公室)和逸夫楼实验室参观交流!

2、主要研究方向

1)硫属半导体材料的设计与合成;

2)红外非线性光学晶体材料的研发;

3)稀土荧光材料的合成及性能表征;

4)大尺寸单晶体的生长(提拉、光浮区、坩埚下降法等)及激光性能测试

3、教育和工作经历

2008/09-2013/06 山东大学晶体材料国家重点实验室，材料学，硕博连读 导师：张怀金教授(杰青)

2013/07-2016/09 中国科学院新疆理化技术研究所，助理研究员

2016/09-2018.8 中国科学院新疆理化技术研究所，副研究员

2018.9- 河北大学，特聘研究员

4、第一及通讯作者文章

1. Kui Wu, Yu Chu, Zhihua Yang, Shilie Pan,* Concurrently wide bandgaps and good nonlinear optical responses in A2SrMIVS4 (A = Li, Na; MIV = Ge, Sn) as new potential infrared nonlinear optical materials. Chem. Sci., 2019, 10,3963. (IF= 9.063)

2. Kui Wu, Shilie Pan,* A review on structure−performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances. Coord. Chem. Rev. 2018, 377, 191-208(IF = 14.499)

3. Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan,* New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials. J. Am. Chem. Soc. 2017, 139, 14885−14888. (IF = 14.357)

4. Guangmao Li, Kui Wu,* Qiong Liu, Zhihua Yang, Shilie Pan,* Na2ZnGe2S6: A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold. J. Am. Chem. Soc. 2016, 138, 7422−7428. (IF = 14.357)

5. Kui Wu, Zhihua Yang, Shilie Pan,* Na2BaMQ4 (M = Ge, Sn; Q = S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations. Angew. Chem. Int. Ed. 2016, 55, 6713–6715. (一区，IF = 12.102)

6. Kui Wu, Zhihua Yang, Shilie Pan,* Na2Hg3M2S8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds. Chem. Mater. 2016, 28, 2795−2801. (IF = 9.890)

7. Kui Wu, Zhihua Yang, Shilie Pan,* A First Quaternary Diamond-like Semiconductor with 10−membered LiS4 Rings Exhibiting Excellent Nonlinear Optical Performances. Chem. Commun. 2017, 53, 3010−3013. (IF = 6.290)

8. Kui Wu, Bingbing Zhang, Zhihua Yang* and Shilie Pan*, Remarkable multimember-ring configurations in a new family of Na7MIISb5S12 (MII = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures. Chem. Commun. 2018, 54, 8269−8272. (IF = 6.290)

9. Kui Wu, Zhihua Yang and Shilie Pan, Na4MgM2Se6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M2Se6]6− Units Exhibiting Large Laser-Damage Thresholds, Inorg. Chem. 2015, 54, 10108. (IF = 4.820)

10. Kui Wu, Xin Su, Shilie Pan, and Zhihua Yang, Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7, Inorg. Chem. 2015, 54, 2772. (IF = 4.820)

11. Yu Chu, Kui Wu,* Xin Su, Zhihua Yang, Shilie Pan*, “Intriguing structural transition inducing variable birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)”. Inorg. Chem. 2018, 57, 11310–11313. (IF = 4.820)

12. Kui Wu, Xin Su, Zhihua Yang, Shilie Pan,* An investigation on new infrared nonlinear optical material: BaCdSnSe4, and three new related centrosymmetric compounds: Ba2SnSe4, Mg2GeSe4, and Ba2Ge2S6, Dalton Trans. 2015, 44, 19856. (IF = 4.177)

13. Kui Wu, Zhihua Yang, Shilie Pan*, Na6Si3S8O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si3S8O]6− units without S–O bonds, Dalton Trans. 2017, 46, 13356. (IF = 4.177)

14. Kui Wu, Liangzhen Hao, Haohai Yu, Zhengping Wang, Jiyang Wang, Huaijin Zhang,* Thermal and laser properties of Nd:Lu3Sc1.5Ga3.5O12 for high power dual-wavelength laser, Opt. Express 2012, 20, 6944. (IF = 3.207)

15. Guangmao Li, Qiong Liu, Kui Wu,* Zhihua Yang and Shilie Pan, Na2CdGe2Q6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses, Dalton Trans. 2017, 46, 2778. (IF = 4.177)

16. Ailijiang Abudurusuli, Kui Wu,* Yilimiranmu Rouzhahong, Zhihua Yang, and Shilie Pan, NaBaMIIIQ3 (MIII = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q6)6− dimers. Dalton Trans., 2018, 47, 16044. (IF = 4.177)

17. Leyan Nian, Kui Wu,* Guijie He, Zhihua Yang, Shilie Pan*, Effect of Element-Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu and Ag; MIV = Si, Ge and Sn; Q = S and Se). Inorg. Chem. 2018, 57, 3434–3442. (IF = 4.820)

18. Ni Zhen, Kui Wu,* Ying Wang, Qiang Li, Wenhui Gao, Dianwei Hou, Zhihua Yang, Huaidong Jiang, Yongjun Dong, Shilie Pan*, BaCdSnS4 and Ba3CdSn2S8: syntheses, structures, and non-linear optical and photoluminescence properties, Dalton Trans. 2016, 45, 10681. (IF = 4.177)

19. Ailijiang Abudurusuli, Kui Wu,* Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan,* Na6Zn3MIII2Q9 (MIII = Ga, In; Q = S, Se): four new supertetrahedron layered chalcogenides with unprecedented vertex-sharing T3-clusters and desirable photoluminescence performances, Inorg. Chem. Front. 2018,

5, 1415. (IF = 4.036)

20. Kui Wu, Shilie Pan*, Zhihua Yang, Ba2GeS4 and Mg2SnS4: synthesis, structures, optical properties and electronic structures, RSC Adv. 2015, 5, 33646. (IF = 3.289)

21. Ailijiang Abudurusuli, Kui Wu,* Shilie Pan*, Four New Quaternary Chalcogenides A2Ba7Sn4Q16 (A=Li, Na; Q=S, Se): Syntheses, Crystal structures, Nonlinear Optical Performances, New J. Chem. 2018, 42, 3350. (IF = 3.269)

22. Leyan Nian, Junben Huang, Kui Wu*, Zhi Su, Zhihua Yang, Shilie Pan*, BaCu2MIVQ4 (MIV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations, RSC Adv. 2017, 7, 29378. (IF = 3.289)

23. Ni Zhen, Leyan Nian, Guangmao Li, Kui Wu *, Shilie Pan*, A high laser damage threshold and a good second-harmonic generation response in a new infrared NLO material: LiSm3SiS7, Crystals 2016, 6, 121. (IF = 2.075)

24. Ailijiang Abudurusulia, Hanqin Ding, Kui Wu*, Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13, J. Solid State Chem. 2017, 255, 133. (IF = 2.316)

25. Yu Chu, Guangmao Li, Xin Su, Kui Wu, Shilie Pan, A review on the development of infrared nonlinear optical materials with triangular anionic groups, J. Solid State Chem. 271 (2019) 266–272

26. Xiaowen Wu, Xiaofeng Gu, Hui Pan, Yi Hu, and Kui Wu*, Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe5, Crystals 2018, 8, 165. (IF = 2.074)

27. Kui Wu, Shilie Pan*, Li2HgMS4 (M = Si, Ge, Sn): new quaternary diamond-like semiconductors for infrared laser frequency conversion, Crystals 2017, 7, 107. (IF = 2.074)

28. Kui Wu, Liangzhen Hao, Huaijin Zhang,* Haohai Yu, Yicheng Wang, Jiyang Wang, Xueping Tian, Zhichao Zhou, Junhai Liu, Robert I. Boughton, Lu3Ga5O12 crystal: exploration of new laser host material for the ytterbium ion, J. Opt. Soc. Am. B 2012, 29, 2320. (IF = 1.731)

29. Kui Wu, Liangzhen Hao, Huaijin Zhang,* Haohai Yu, Hengjiang Cong, Jiyang Wang, Growth and characterization of Nd:Lu3ScxGa5−xO12 series laser crystals, Opt. Commun. 2011, 284, 5192. (IF = 1.480)

30. Kui Wu, Bin Yao, Huaijin Zhang,* Haohai Yu, Zhengping Wang, Jiyang Wang, Minhua Jiang, Growth and properties of Nd:Lu3Ga5O12 laser crystal by floating-zone method, J. Cryst. Growth 2010, 312, 3631. (IF = 1.462)

31. Guangmao Li, Kui Wu,* Qiong Liu, Zhihua Yang, Shilie Pan*, Na2ZnSn2S6: A Mixed-metal Thiostannate with Large Second-harmonic Generation Response Activated by Penta-tetrahedral [ZnSn4S14]10- Clusters, Sci. China Technol. Sci. 2017, 60, 1465. (IF = 1.719)

32. Kui Wu, Shilie Pan*, Hongping Wu, Zhihua Yang, Synthesis, structures, optical properties and electronic structures of PbGa2Q4 (Q=S, Se) crystals, J. Mol. Struct. 2015, 1082, 174. (IF = 1.78)

5、承担科研项目

主持科研项目共11项。

1)国家自然科学基金面上项目，2019/1-2022/12，60万元

2)国家自然科学基金青年项目，2015/01-2017/12，25万元，已结题

3)中科院科研装备研制项目，2018/1-2019/12，295万元

4)“万人计划”后备-青年拔尖人才(全疆3人)，2017/6-2018/6，10万元

5)中科院西部之光“西部博士”项目，2013/09-2017/08，40万元

6)新疆自治区重点实验室开放课题，2017/1-2019/12，20万元

7)新疆自治区自然科学基金面上项目，2018/7-2021/6，7万元

8)新疆自治区青年科技创新人才培养工程，2014/10-2016/09，5万元

9)新疆自治区自然科学基金青年项目，2014/01-2016/12，5万元

10)中科院重点实验室开放课题，2016/1-2018/12，2万元

11)企业委托项目，2015/01-2016/12，25万元

6、授权专利

目前已申请中国发明专利14项，授权6项。

(1) 张怀金，武奎，于浩海，王继扬，一种石榴石结构复合激光晶体的制备方法，2015.4.22， 201210016934.5

(2) 张怀金，武奎，于浩海，王继扬，一种多段掺杂浓度梯度的石榴石复合晶体及其生长方法，2014.11.5，201210016919.0

(3) 张怀金，武奎，于浩海，王继扬，激光激活离子掺杂浓度梯度的钒酸盐复合晶体及其制备方法，2014.10.22，201210016920.3

(4) 张怀金，武奎，于浩海，王继扬，一种具有锆英石结构钒酸盐复合激光晶体的制备方法，2014.9.10，201210016946.8

(5) 于浩海，武奎，郝良振，王正平，张怀金，王继扬，Nd:YGG晶体1111 nm激光器及在一氧化碳中毒检测中的应用，2012.7.11，201110006592.4

(6) 张怀金，武奎，郝良振，于浩海，王继扬，高温稀土氧化物激光晶体及其制备方法，2012.2.15，201010190075.2

7、获奖情况

2014年 新疆自治区科技进步一等奖(排名12)

2015年 乌鲁木齐市科技进步一等奖(排名5)

2015年 新疆第十届青年学术年会优秀论文一等奖

2016年 2016年自治区自然科学优秀学术论文二等奖

2015年 新疆创新创业大赛第4名(三等奖)

2012年 博士研究生国家奖学金